Not many people may be aware, but we are in contact with different types of resins even if we are not walking in the woods. There are resins in the car that takes us out and about, in the mobile phone we are constantly looking at, and in the floor we walk on. And yes, also in the plane that flies us to our next holiday destination. Modern life as we know it would be hard to imagine without resins, especially epoxies. Used in countless applications across industry, epoxies are one of the most adaptable and widely sold high-performance polymers on the planet.
Epoxy resins have been commonly used since the 1930s, when Swiss scientist Pierre Castan made a smoothie-like mix with a thermoset polymer and a hardener, binding them together in a chemical reaction called “curing”. Years later in the US, scientist Sylvain Greenlee applied a similar principle to develop a low-molecular resin known as BADGE – now the most widely used epoxy resin in the world.
Modern epoxies are versatile substances which, depending on the desired outcome, can be blended in different grades, from liquid to almost solid. Today there are more than 50 different types of epoxies in commercial use. There are also hundreds of hardeners to modify their properties to satisfy the most demanding and unique requirements. Well over 250,000 tonnes of resin are used every year in Europe in applications ranging from flooring to sewage pipes, from sports goods to electronics, from automotive to aerospace.
When did epoxies take off?
It was 1947 when Howard Hughes, the US visionary aviator and aircraft designer, used epoxies for the first time in the construction of his airlift flying boat “Spruce Goose”. This aircraft, also known as HK-4 Hercules, was designed during World War II to transport cargo and troops over long distances. Its massive size and distinctive wooden construction – assembled with three layers of epoxy glue – made it an American icon. Epoxies and aircraft design have been inseparable ever since.
The first modern use of epoxy resins in aircraft design dates back to about 40 years ago when boron-reinforced epoxy composite was used for the skins of the empennages of US fighter aircrafts F14 and F15. At first, epoxy-based composite materials were used only in secondary structures, but soon engineers realised that their use in primary structures, such as wings and fuselages, would improve the performance of the whole aircraft. In fact, while the F15 used around 2% of composite material, the F18 included 19% and the F22 a sizeable 24%.
The flight to commercial aircrafts
It did not take long for commercial aircrafts to follow the footsteps of trailblazing defence applications using epoxy-based composites. The main advantages were that composite material reduces airframe weight, which enables better fuel economy, lower operating costs and lower CO2 emissions. European conglomerate Airbus saw this potential and, in the 1980s, started to apply composite materials in the rudder of some of its commercial aircrafts such as the A300 and A310.
Composite tail fins were next, leading to a reduction in the 2,000 pieces initially needed for the metal-based version to fewer than 100 as well as lower weight and production costs.
Structural and performance assets today
All these improvements in aircraft design led us to the current models, such as the workhorse Airbus aircraft -the A320-, which features a tail structure made entirely of carbon-fibre reinforced composite material. In addition, its floor panels are made of glass-fibre reinforced epoxy polymer, lowering the total composite airframe weight by 28%. The iconic Airbus A380, the largest commercial passenger plane in the world, carries around 28% composite material by weight. Likewise, Boeing’s hot-seller, the 787 Dreamliner, features around 50% composite materials leading to an average weight saving of about 20%, while Airbus’ counter offer, the A350 XWB, with a fuselage made entirely of carbon-fibre composite, soars to new heights with an overall composite content of 52%. In defence aviation, about 75% of the current European Eurofighter exterior area uses a toughened epoxy skin and, in total, about 40% of its structural weight is made up of carbon-fibre reinforced composite material.
However, structural composite applications are not epoxy’s only big success. They have played a major role in combining and finishing structural parts but they are also crucial to make them last. Epoxy resins are essential in anti-corrosion coatings and adhesive applications which, at the same time, are great at replacing or complementing heavier bonding methods like mechanical fasteners.
Epoxy-based composite materials have become indispensable in aircraft building. In the next 20 years more than 30,000 new aircraft deliveries are expected, while about 10,000 existing airplanes will need to be refitted and maintained. Design and maintenance efforts are primarily targeting weight reductions for better fuel economy and lowering service costs to ultimately reduce operating costs, thus helping airlines operate successfully in a fiercely competitive global environment.
Sustainability aspects, like lower fuel emissions, are an important side benefit of structural weight reductions. In fact, CO2 emissions are already targeted by regulatory authorities, and future emissions goals present a challenge for the aerospace industry and global carriers. In this sense, electric airplanes might contribute to curb and ultimately reduce future emission growth. Their development will further increase the demand for lightweight airframe structures to offset the weight of the potentially enormous battery packs. A similar development can already be witnessed in the e-car mobility arena at the moment.
There is a bright future ahead for epoxies used in aerospace applications and beyond. Epoxy resin producers are not idly sitting back in anticipation of future growth bonanzas. Whatever technical challenges new applications may present, the epoxy industry is already preparing today to be able to deliver cutting-edge solutions which will enable the innovations of tomorrow fly even higher.